4-Methyl-N-(4-methylbenzoyl)benzenesulfonamide
نویسندگان
چکیده
In the title compound, C(15)H(15)NO(3)S, the conformation of the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. The dihedral angle between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment is 84.9 (1)° and that between the sulfonyl and the benzoyl benzene rings is 89.0 (1)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur.
منابع مشابه
4-Methyl-N-(2-methylbenzoyl)benzenesulfonamide
In the title compound, C(15)H(15)NO(3)S, the conformation of the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. Further, the conformation of the C=O bond is syn to the ortho-methyl group in the benzoyl ring. The dihedral angle between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment is 87.1 (1)° and that between the sulfonyl and the benzoyl benzene rings is 58.2 (1)°. I...
متن کامل4-Chloro-N-(3-methylbenzoyl)benzenesulfonamide monohydrate
In the title compound, C(14)H(12)ClNO(3)S·H(2)O, the dihedral angle between the sulfonyl and benzoyl benzene rings is 84.4 (2)°. In the crystal, every water mol-ecule forms four hydrogen bonds with three different mol-ecules of 4-chloro-N-(3-methyl-benzo-yl)benzene-sulfonamide. One of the water H atoms forms a bifurcated hydrogen bond with both the sulfonyl and the carbonyl O atoms of the same ...
متن کامل2-Methyl-N-(2-methylbenzoyl)benzenesulfonamide
In the title compound, C(15)H(15)NO(3)S, the 2-methyl-phenyl ring bonded to the sulfonyl group is disordered with site-occupation factors of 0.75:0.25. The dihedral angles between the two aromatic rings are 67.6 (1) and 69.2 (1)° for the major and the minor occupied sites, respectively. In the crystal, mol-ecules are linked into centrosymmetric dimers by pairs of N-H⋯O hydrogen bonds.
متن کامل2-Methyl-N-(3-methylbenzoyl)benzenesulfonamide
In the title compound, C(15)H(15)NO(3)S, the sulfonyl and amide-bound benzene rings are oriented at dihedral angles of 83.1 (1) and 22.5 (3)°, respectively, with the almost planar S-N-C=O segment (r.m.s. deviation = 0.003 Å). The dihedral angle between the two benzene rings is 74.8 (1)°. In the crystal structure, pairs of mol-ecules are linked into centrosymmetric dimers by pairs of N-H⋯O hydro...
متن کامل4-Chloro-N-(2-methylbenzoyl)benzenesulfonamide
In the title compound, C(14)H(12)ClNO(3)S, the conformation of the N-H bond in the C-SO(2)-NH-C(O) segment is anti to the C=O bond. The two aromatic rings are tilted relative to each other by 57.7 (1)°. In the crystal, mol-ecules are linked by pairs of N-H⋯O(S) hydrogen bonds, forming centrosymmetric dimers.
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